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The Polarizaton of Ions in Metal Azides and Its Influence the Properties 癴 Azides
Pages: 40-49
Year: Issue:  2
Journal: Transactions of Beijing Institute of Technology

Keyword:  迭氮化物离子极化氮化合物热分解机理晶体结构电离势电子云密度起爆药非对称型能带结构;
Abstract: Through calculation with the HMt) method it is indicated that N"J is easily polarized. The degree of polarization of ions in the crystals of metal azides is dependent on the value z*a/r of cations in azides. As primary explosives the properties of azides are ralated to the polarization. The influence of the pola-rizBtion on the structure of crystals, tjie structure of energy band and the me-canism of slow decomposition is discussed
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