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Kinetics of n-polymer Irreversible Aggrevation Processes with Removal Term
Author(s): Xue Yu, Chen Guangzhi
Pages: 25-
27
Year: 1999
Issue:
1
Journal: GUANGXI SCIENCES
Keyword: 不可逆聚集过程; 液胶-凝胶相变; 迁移项; 定态;
Abstract: 利用n体不可逆聚集过程的动力学方程(广义Smolucho vski方程),讨论了系统存在迁移作用时n体不可逆聚集过程的动力学行为,给出迁移项为S(t)=-a(t)Cm(t)-b(t)mCm(t)的广义Smoluchovski方程的解析解;而且得出了液胶(Sol)-凝胶(Gel)相变的条件.同时,本文还讨论n体不可逆聚集过程中非凝胶系统所出现的定态;当b(t)=0时,凝胶系统发生液胶-凝胶相变的时间与非凝胶系统处于定态的时间相同.
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