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The Pyrolysis Mechanism of 1,1,2,2-Tetramethyl-1,2-Dichlorodisilane
Author(s): 
Pages: 7-10
Year: Issue:  1
Journal: Guangzhou Chemistry

Abstract: 利用量子化学知识对典型的二硅烷高沸物1,1,2,2-四甲基-1,2-二氯二硅烷的裂解机理进行理论研究.结果表明,在无催化剂和常温常压下,1,1,2,2-四甲基-1,2-二氯二硅烷以CHCl3作为裂解气的反应分为两步进行,均为放热反应,其速控步第一步的正反应活化能为352.949 kJ/mol.
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