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Issue:
Kinetic Modeling for the Oxidation of Methanol in Supercritical Water
Author(s):
JIANG Chengfa
,
WANG Zuo
Pages:
35
-
39
Year:
2004
Issue:
5
Journal:
JOURNAL OF SICHUAN UNIVERSITY(ENGINEERING SCIENCE EDITION)
Keyword:
甲醇
;
超临界水氧化
;
动力学模型
;
Abstract:
为了研究超临界水氧化有机污染物的反应动力学,采用甲醇作为超临界水氧化的研究对象,根据超临界水氧化甲醇的反应机理,运用质量守恒原理和似稳态假定,建立超临界水氧化甲醇的动力学模型.用实验数据关联动力学模型,得出超临界水氧化甲醇的反应速率常数,再用建立的动力学模型计算出甲醇的转化率和甲醛、CO和CO2的产率,并与实验值进行比较.结果表明,计算值与实验数据能较好地吻合.
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