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Algebraic studies of high vibration energy spectrum and potential energy surface of S2O
Author(s): 
Pages: 281-285
Year: Issue:  2
Journal: JOURNAL OF ATOMIC AND MOLECULAR PHYSICS

Keyword:  S2O能谱势能面;
Abstract: 本文利用代数方法研究了非对称弯曲三原子分子S2O分子处于C~1A′电子态的能谱及其稳定构型下的势能面,通过对30条光谱数据的拟和得到的RMS误差为2.40 cm-1.结果表明,利用此代数Hamiltonian很好的实现了能级再现,它预测了振动总量子数达到20的全部振动能级(在本文中我们只列举到v=9),同时我们计算了分子的解离能与力常数.通过与实验值比较证明了这种方法在计算这类分子的有效性.
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