Synthesis and Properties of the Fused Aza-polynitrocyclic Compounds
Author(s): Zhang Junlin, Xiao Chuan, Zhai Lianjie, Wang Xijie, Bi Fuqiang, Wang Bozhou, Xi’an Modern Chemistry Research Instritute
Pages: 1197-1207
Year: 2016 Issue: 6
Journal: Chinese Journal of Organic Chemistry
Keyword: energetic compounds; fused aza-polycyclic structure; synthesis; N-nitration; properties;
Abstract: Fused aza-polycyclic structures play an important role in the synthesis of energetic compounds and the presence of NNO2 groups renders them a rich source of energy. Currently, fused aza-polynitrocyclic compounds have gained considerable prominence as novel energetic compounds. This review focuses on the synthesis of various ring skeletons of the aza-bicyclic, aza-polycyclic and aza-propellane-derivatized energetic compounds as well as the studies of N-nitration, physicochemistry and detonation properties. The synthesis of pentaaza[3.3.3]propellane and hexaaza[3.3.3]propellane is highlighted and N-nitration explorations of these high-strained unstable skeletons are discussed in details.
Pages: 1197-1207
Year: 2016 Issue: 6
Journal: Chinese Journal of Organic Chemistry
Keyword: energetic compounds; fused aza-polycyclic structure; synthesis; N-nitration; properties;
Abstract: Fused aza-polycyclic structures play an important role in the synthesis of energetic compounds and the presence of NNO2 groups renders them a rich source of energy. Currently, fused aza-polynitrocyclic compounds have gained considerable prominence as novel energetic compounds. This review focuses on the synthesis of various ring skeletons of the aza-bicyclic, aza-polycyclic and aza-propellane-derivatized energetic compounds as well as the studies of N-nitration, physicochemistry and detonation properties. The synthesis of pentaaza[3.3.3]propellane and hexaaza[3.3.3]propellane is highlighted and N-nitration explorations of these high-strained unstable skeletons are discussed in details.
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