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STUDY ON THE KINETICS OF ALKYLATION OF BENZENE WITH LONG CHAIN OLEFINS OVER SOLID ACID CATALYST
Author(s): 
Pages: 73-78
Year: Issue:  z1
Journal: ACTA PETROLEI SINICA

Keyword:  固体酸烯烃烷基化动力学;
Abstract: 根据苯与长链烯烃烷基化反应动力学方程,笔者利用在负载杂多酸中孔分子筛催化剂上液-固相反应的实验数据进行参数估值,确定了反应速率常数、扩散系数、反应活化能和扩散活化能参数,建立了考虑内扩散影响的苯与长链烯烃烷基化反应动力学模型.结果表明,所建动力学模型具有较高的计算精度,符合苯与长链烯烃烷基化反应规律.
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