Synthesis and Living Polymerization Characteristics of 2,2,2-Trifluoroethyl Methacrylate in Supercritical CO2 Based on RAFT Polymerization
Author(s): LI Guanghan, YANG Shuaishuai, XU Anhou, ZHANG Shuxiang, Shandong Engineering Research Center for Fluorinated Material, Shandong Key Laboratory of Fluorine Chemistry and Chemical Engineering Materials, School of Chemistry and Chemical Engineering, University of Jinan
Pages: 357-361
Year: 2014 Issue: 5
Journal: Journal of Jinan University(Science and Technology)
Keyword: supercritical CO2; RAFT polymerization; 2; 2; 2-trifluoroethyl methacrylate; fluorescent controllable polymerization;
Abstract: A polymer of 2,2,2-trifluoroethyl methacrylate( TFEMA) was prepared in supercritical CO2based on RAFT polymerization with cumyl dithiobenzoate( CDB) as chain transfer agent,and characterized by means of FT-IR,1H NMR,DSC and GPC methods. The results indicated that the polymer has a clear structure with controllable molecular weight and narrow distribution.
Pages: 357-361
Year: 2014 Issue: 5
Journal: Journal of Jinan University(Science and Technology)
Keyword: supercritical CO2; RAFT polymerization; 2; 2; 2-trifluoroethyl methacrylate; fluorescent controllable polymerization;
Abstract: A polymer of 2,2,2-trifluoroethyl methacrylate( TFEMA) was prepared in supercritical CO2based on RAFT polymerization with cumyl dithiobenzoate( CDB) as chain transfer agent,and characterized by means of FT-IR,1H NMR,DSC and GPC methods. The results indicated that the polymer has a clear structure with controllable molecular weight and narrow distribution.
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