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zai fermi he coriolis gong zhen zuo yong xia huan bing wan v9+v10 he pin de gao fen bian lv hong wai guang pu
Author(s): 
Pages: 491
Year: Issue:  Z1
Journal: Chinese Journal of Lasers

Keyword:  环丙烷区域内傅里叶变换红外光谱仪高分辨率激光光谱相互作用反常现象最小二乘方分子振动对称陀螺转动结构;
Abstract: <正> 红外高分辨率激光光谱技术为我们提供了研究分子振动和转动相互作用精细情节的有力工具。作者在Nicolet-7199傅里叶变换红外光谱仪上作出了环丙烷在2430~2530cm(-1)区域内分辨率为0.06cm-1的光谱,在2450~2470cm-1区域内出现一个清晰的垂直谱带,归属为v9+v10。在进一步把所有转动结构归属后,用计算机把各子Q支频率值代入通常的对称陀螺垂直谱带公式进行最小二乘方拟合,发现两个明显的反常现象:K2项的系数[(C″-C′)-
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