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Thermal Simulation Experiments and Kinetics on the System of Crude Oil and Magnesium Sulfate
Author(s): ZHANG Yonghan, YUE Changtao, LI Shuyuan, ZHONG Ningning
Pages: 994-
1001
Year: 2011
Issue:
5
Journal: Acta Sedimentologica Sinica
Keyword: TSR; crude oil; active sulfur; thermal-simulation experiments; kinetics;
Abstract: 利用高压釜反应装置,在一定温度和压力下考察了吐哈原油和胜利原油与硫酸镁的热化学还原反应,热模拟实验在350~450℃含水条件下进行。利用库仑仪和气相色谱仪对反应后的气体产物进行分析,油相的总硫含量用库仑仪进行测定,固体产物组成利用红外光谱仪与X射线衍射仪进行分析,并对反应动力学进行了研究。结果表明,原油中的LSC含量对TSR的反应程度有重要影响,含量越高,TSR反应程度越强烈。根据动力学模型,计算...
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