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Pulsed Laser Ablation Synthesis Octa (methylsilsesquioxane)
Author(s): ZHOU Yinan, ZHOU Yong, ZUO Fulin
Pages: 28-
29
Year: 2000
Issue:
4
Journal: CHEMICAL ENGINEER
Keyword: 激光溅射; 合成; 硅氧烷;
Abstract: 以脉冲激光溅射作用于聚甲基硅氧烷,经真空升华,直接得到了一种产物的单晶.经X-射线晶体衍射测定确定其为具有(CH3SiO1.5)8组成的硅氧烷.该种产物具有多环立体空间构型.结果表明,在脉冲激光的作用下,反应物的链状结构发生解离,并在等离子体条件下进行结构重组,生成了具有立体空间构型的产物.
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