Thermal Safety of 1,1 \'-Dimethyl-5,5\'-azotetrazole and 2, 2\'- Dimethyl-5 ,5\'-azotetrazole
Author(s): HU Rong-zu, GAO Hong-xu, ZHAO Feng-qi, ZHAO Hong-an, WANG Xi-jun, ZHANG Hai, MA Hai-xia
Pages: 126-131
Year: 2011 Issue: 2
Journal: Chinese Journal of Energetic Materials
Keyword: 物理化学; 1; 1\'-二甲基-5; 5\'-偶氮四唑一水合物; 2; 2\'-二甲基-5; 5\'-偶氮四唑; 热安全性;
Abstract: 借助不同加热速率(β)的非等温DSC曲线离开基线的初始温度(To)、onset温度(Te)和峰顶温度(Tp),采用Kissinger法和Ozawa法求得热分解反应表观活化能(Ek和Eo)和指前因子(AK),Hu-Zhao-Gao方程求得beO(or pO),Zhao-Hu-Gao方程求得aeo(or pO),微热量法确定的比热容(Cp),以及密度(ρ)、热导率(λ)和分解热(Qd,取爆热之半)数据...
Pages: 126-131
Year: 2011 Issue: 2
Journal: Chinese Journal of Energetic Materials
Keyword: 物理化学; 1; 1\'-二甲基-5; 5\'-偶氮四唑一水合物; 2; 2\'-二甲基-5; 5\'-偶氮四唑; 热安全性;
Abstract: 借助不同加热速率(β)的非等温DSC曲线离开基线的初始温度(To)、onset温度(Te)和峰顶温度(Tp),采用Kissinger法和Ozawa法求得热分解反应表观活化能(Ek和Eo)和指前因子(AK),Hu-Zhao-Gao方程求得beO(or pO),Zhao-Hu-Gao方程求得aeo(or pO),微热量法确定的比热容(Cp),以及密度(ρ)、热导率(λ)和分解热(Qd,取爆热之半)数据...
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