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Synthesis of Trifloxystrobin
Author(s): 
Pages: 187-191,212
Year: Issue:  3
Journal: Agrochemicals

Keyword:  杀菌剂肟菌酯邻羟甲基苯甲酸内酯合成;
Abstract: [方法]以苯酞为主要原料,先与双(三氯甲基)碳酸酯(BTC)开环反应生成邻氯甲基苯甲酰氯,再与氰化钠反应得到邻氯甲基苯甲酰氟,甲醇酯化,然后与甲氧基胺盐酸盐肟化,最后与间三氟甲基苯乙酮肟缩合得到肟菌酯.[结果]合成路线5步总收率22%.[结论]该工艺简单经济,条件温和,适合工业化生产.
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