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Synthesis and Fluorescent Properties of o-Phenylenediamine and Its Metal Coordination-Complexes Based Fluoropoly(amide-sulfonamide)s
Author(s): 
Pages: 1-6
Year: Issue:  1
Journal: Journal of Functional Polymers

Keyword:  o-phenylenediamine based fluoropoly(amide-sulfonamide)smetal coordination polymersolution polycondensationfluorescence quantum yield;
Abstract: 采用溶解聚合法使β-四氟乙烷磺内酯分别与邻苯二胺、二氯-邻苯二胺合锌(II)和二氯-邻苯二胺合镉(II)开环缩聚,制备出邻苯二胺型和金属配位邻苯二胺型含氟聚酰胺磺酰胺聚合物.通过红外光谱、核磁共振氢谱、电感耦合等离子体发射光谱仪、凝胶渗透色谱等手段,确定其分子链为同时含有酰胺、磺酰胺、氟碳基团、芳环和金属离子的特殊结构;采用紫外-可见分光光度计和荧光分光光度计分析表明:邻苯二胺型含氟聚酰胺磺酰胺具...
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