Author(s): ZHANG Hao, DING Juan, ZHANG Yawen, SHEN Zongxuan(keylaboratoryoforganicsynthesisofjiangsuprovince, COLLEGE Ofchemistryandchemicalengineering, SUZHOU University, suzhou, 215006)
Pages: 44-46
Year: 2005 Issue:  1
Journal: Journal of Suzhou Railway Teachers College(Natural
Keyword:  手性;  氨基醇;  合成;
Abstract: L-脯氨酸经3步反应制得手性氨基醇(S)-(二苯基羟甲基)四氢吡咯。该化合物分别与苄溴及β-溴甲基萘反应得到两种手性氨基醇二苯基-犤(S)-1-苄基四氢吡咯基犦甲醇和二苯基-犤(S)-1-(β-萘甲基)四氢吡咯基犦甲醇,产率分别为41.1%和32.5%。