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AB INITIO STUDY OF INFLUENCE OF -CHCH_2 AND-CHO SUBSTITUENTS ON STABILITY AND STRAIN ENERGIES OF CYCLOPROPANE
Author(s): 
Pages: 49-54
Year: Issue:  1
Journal: Yantai Teachers University journal(Natural Science

Keyword:  vinylcyclopropanecyclopropanecafboxaldehydestabilitystrain energy;
Abstract: 用Dunning基对乙烯基环丙烷、醛基环丙烷进行了从头计算。根据所得数据,在电子效应和成键规律方面探讨了乙烯基、醛基对三元环的影响。得出三元环的稳定性(中心电荷密度的大小)与取代基的σ、π效应有关,而张力能只与取代基的π效应有关。
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