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Estimation of Critical Temperature of Thermal Explosion for Some Furazano-fused Cyclic Compounds Using Non-isothermal DSC
Pages: 635-642
Year: Issue:  6
Journal: Chinese Journal of Energetic Materials

Keyword:  physical chemistryfurazano-fused cyclic compoundscritical temperaturethermal explosionnonisothermal DSC;
Abstract: 通过合理假设,从谢苗诺夫(Semenov)热爆炸理论和8个非等温动力学方程,导出了估算含能材料(EMs)热爆炸临界温度(T_b)的2个通式和它们的6个派生式.从EMs的非等温DSC曲线可获得DSC曲线偏离基线的起始温度(T_0)、onset温度(T_(ei))和放热分解反应的动力学参数.由方程T_(0i or ei)=T_(oo or e0)α_1β_i+α_2β_i~2+…α_(L-2)+β_i...
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