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Crystal Structure and Laser Sensitivity of Cobalt(Ⅲ)Complex[Co(NH_3)_4(N_3)_2]ClO_4
Author(s): 
Pages: 694-698
Year: Issue:  6
Journal: Chinese Journal of Energetic Materials

Keyword:  physical chemistrycobalt(Ⅲ)complexcrystal structurelaser sensitivity;
Abstract: 制备了高氯酸·四氨·双叠氮基合钴(Ⅲ)(DACP)的单晶,用X-ray单晶面探衍射仪测定了其晶体结构.结果表明,晶体属三斜晶系,空间群为P-1.晶体学参数为:a=0.74229(9)nm,α=93.244(2)°b=1.21273(14)nm,β=100.074(2)°;c=1.8124(2)nm,γ=98.033(2)°.晶胞体积V=1.5851(3)nm~3,晶胞分子数Z=6,计算密度D_c=...
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