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Theory and Numerical Method of Calculating the Kinetic Parameters of Exothermic Decomposition Reaction of Energetic Materials from Peak Temperature of DSC Curves at Constant Heating Rates
Author(s): 
Pages: 643-649
Year: Issue:  6
Journal: Chinese Journal of Energetic Materials

Keyword:  physical chemistryDSCkinetic parameterKooij\'s formulavan\'t Hoff FormulaKeto-RDXnon-isothermal;
Abstract: 根据Kooij公式和van\'t Hoff公式,从恒速升温速率下的DSC曲线峰温导出了计算含能材料放热分解反应动力学参数的两个数学表达式,提出了计算相应动力学参数的数值方法.对1,3,5-三硝基-1,3,5-三氮杂环己酮-2(Keto-RDX),由导出的两个表达式、Kissinger法、Ozawa法、Tang法、Hu-Gao-Zhang法、非线性等转化率积分法(NL-INT)所得的活化能E值彼此接近...
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