Synthesis and Crystal Structure of a New 3D Supramolecular Polyoxometalate (4,4'-bipy){[Ag(4,4'-bipy)]3[PMoⅥ12O40]}·H2O
Author(s): WANG Xiao-Lan, WANG En-Bo, XU Xin-Xin, LI Yang-Guang
Pages: 1937-1940
Year: 2008 Issue: 10
Journal: CHEMICAL JOURNAL OF CHINESE UNIVERSITIES
Keyword: 多金属氧酸盐; 晶体结构; 超分子; 银;
Abstract: 利用H3PMo12O40·4H2O,4,4'-bipy和AgNO3反应,在中温水热条件下合成了一种新颖的三维超分子多金属氧酸盐 (4,4'-bipy){[Ag(4,4'-bipy)]3 [PmoⅥ12O40]}· H2O(1),并通过元素分析、红外光谱、热重分析和X射线单晶衍射对其结构进行了表征.结果表明,该化合物属三斜晶系,P1空间群,晶胞参数a=1.1275(2)nm,b=1.1910(2)nm,c=1.2898(3)nm,α= 112.63(3)°,β=94.63(3)°,γ=99.53(3)°,V=1.5567(5)nm3,Z=1.该化合物具有三维超分子结构及荧光性质.
Pages: 1937-1940
Year: 2008 Issue: 10
Journal: CHEMICAL JOURNAL OF CHINESE UNIVERSITIES
Keyword: 多金属氧酸盐; 晶体结构; 超分子; 银;
Abstract: 利用H3PMo12O40·4H2O,4,4'-bipy和AgNO3反应,在中温水热条件下合成了一种新颖的三维超分子多金属氧酸盐 (4,4'-bipy){[Ag(4,4'-bipy)]3 [PmoⅥ12O40]}· H2O(1),并通过元素分析、红外光谱、热重分析和X射线单晶衍射对其结构进行了表征.结果表明,该化合物属三斜晶系,P1空间群,晶胞参数a=1.1275(2)nm,b=1.1910(2)nm,c=1.2898(3)nm,α= 112.63(3)°,β=94.63(3)°,γ=99.53(3)°,V=1.5567(5)nm3,Z=1.该化合物具有三维超分子结构及荧光性质.
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