Efficient Synthesis of Octalone
Author(s): ZHANG Chen, CHEN Jin-chun, ZHENG Guo-jun, LI Yu-lin
Pages: 276-279
Year: 2007 Issue: 3
Journal: CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
Keyword: Octalone; (±)-1β; 11-Dihydroxy-Δ4-eudesmol; Cationic cyclization; Sesquiterpenoids; Total synthesis;
Abstract: A highly efficient and convergent approach for the synthesis of octalone 1, the focal intermediate for the synthesis of several sesquiterpenoids, was developed based on the cationic cyclization strategy of the functionalized oxabicyclic template 5.
Pages: 276-279
Year: 2007 Issue: 3
Journal: CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
Keyword: Octalone; (±)-1β; 11-Dihydroxy-Δ4-eudesmol; Cationic cyclization; Sesquiterpenoids; Total synthesis;
Abstract: A highly efficient and convergent approach for the synthesis of octalone 1, the focal intermediate for the synthesis of several sesquiterpenoids, was developed based on the cationic cyclization strategy of the functionalized oxabicyclic template 5.
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