A new chain-like heteropolytungstate formed by Keggin cluster units: Synthesis and structure of [H2bpy]3[SiMnW11O39]·1.25H2O
Author(s): Jing Xin Meng, Ying Ma, Xin Xin Xu, Yang Guang Li, En Bo Wang
Pages: 81-84
Year: 2007 Issue: 1
Journal: CHINESE CHEMICAL LETTERS
Keyword: Heteropolytungstate; Keggin clusters; Zigzag chain;
Abstract: A new heteropolytungstate, [H2bpy]3[SiMnW11O39]· 1.25H2O(1), has been prepared under mild hydrothermal conditions and structurally characterized by single crystal X-ray diffraction. It is the first characterized compound containing 1D zigzag chain of transition metal substituted Keggin heteropolytungstate, which is connected through a common oxygen atom. The elemental analysis and IR of it are also described.
Pages: 81-84
Year: 2007 Issue: 1
Journal: CHINESE CHEMICAL LETTERS
Keyword: Heteropolytungstate; Keggin clusters; Zigzag chain;
Abstract: A new heteropolytungstate, [H2bpy]3[SiMnW11O39]· 1.25H2O(1), has been prepared under mild hydrothermal conditions and structurally characterized by single crystal X-ray diffraction. It is the first characterized compound containing 1D zigzag chain of transition metal substituted Keggin heteropolytungstate, which is connected through a common oxygen atom. The elemental analysis and IR of it are also described.
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