Author(s): WU Sheng-xi, BAO Bin, WANG Jian-wen, YANG Yong-zhong
Pages: 91-93
Year: 2006 Issue:  1
Journal: CHINESE JOURNAL OF SYNTHETIC CHEMISTRY
Keyword:  乙基环己烷甲酸; 无机碱; 异构化;
Abstract: 通过顺-4-乙基环己烷甲酸的异构化反应制备了反-4-乙基环己烷甲酸.优化反应条件为:4-乙基环己烷甲酸634 mmol,无机碱与4-乙基环己烷甲酸的摩尔比为1.3:1.0,氮气压力5.0 MPa,温度210℃,反应时间8h,反-4-乙基环己烷甲酸与顺-4-乙基环己烷甲酸的质量比可达98:2.